7
Following materials can be used as ammenments in calcareous soils to reduce the calcareousness
(A) . Alluminium sulphate
(B) . Ammonium polysulfide
(C) . Elemental sulphur
(D) . Sulphuric acid
Choose the correct answer from the options given below:
EXPLANATION
Soil Experimental Designs
- Amendments in Calcareous Soils: Calcareous soils contain free calcium carbonate ($CaCO_3$) that buffers soil pH above 7.5–8.2. Ameliorating high calcareousness requires acid-producing amendments:
- Aluminium sulphate: Hydrolyzes in soil water to produce sulphuric acid and aluminum hydroxide.
- Ammonium polysulfide: Undergoes microbial oxidation to yield sulphuric acid while supplying ammonium-N.
- Elemental sulphur: Oxidized by soil Thiobacillus bacteria into sulphuric acid: $2S + 3O_2 + 2H_2O \rightarrow 2H_2SO_4$.
- Sulphuric acid: Directly neutralizes $CaCO_3$ into soluble calcium sulphate (gypsum).
- Conclusion: All four materials (A, B, C, D) are effective amendments. (Correct answer: Option 3)
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